Mayr's Database of Reactivity Parameters

H-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1-methylsiletane
C4H10Si *
 dichloromethane

N  Param.: 2.30

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1-methylsilolane
C5H12Si *
 dichloromethane

N  Param.: 2.20

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
triethoxysilane
C6H16O3Si *
 dichloromethane

N  Param.: -1.80

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dimethyl(propoxy)silane
C5H14OSi *
 dichloromethane

N  Param.: 2.40

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
triethylgermane
C6H16Ge *
 dichloromethane

N  Param.: 4.00

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetrahydroborate ion (in water)
*
 water

N  Param.: 12.10

sN Param.: 0.79		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
cyanoborate ion (in water)
*
 water

N  Param.: 9.99

sN Param.: 0.54		 *** Org. Biomol. Chem. 2023, 21, 85-88
10.1039/D2OB02041F
tetraethylsilane
*
 MeCN

N  Param.: -6.50

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
butyltrimethylsilane
*
 dichloromethane

N  Param.: -5.40

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(phenethyl)silane
*
 dichloromethane

N  Param.: -3.50

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839