C-Nucleophiles (572)Alkenes (56)Alkyl, Alkenyl and Aryl Boron Compounds (38)Alkynes (1)Allyl Element Compounds (38)Arenes (42)Azolium enolates (4)Breslow intermediates (11)Carbanions (155)Carbenes (NHCs) (7)Enol Ethers (52)Enamines, Enamides, and Ynamides (74)Diazo Compounds and Hydrazones (22)Isonitriles (5)Metal-π-Complexes (5)Metallocenes (6)NHOs (conventional and mesoionic) (19)Vinylsilanes (7)Ylides (30)H-Nucleophiles (193)Halide Anions (29)O-Nucleophiles (138)N-Nucleophiles (319)Aliphatic amines (104)Aromatic amines (7)Amide anions (N reactivity) (21)Amidines and Imines (10)Amino acids (20)Azoles and Azole Anions (33)Guanidines (8)Hydrazines, Hydroxylamines etc. (21)Imidazolines and related compounds (10)Isothioureas (12)Nucleobases and Their Subunits (15)Pyridines, Quinolines etc. (48)Other N-centered nucleophiles (10)S- and Se-Nucleophiles (33)P-Nucleophiles (18)C-Electrophiles (330)N-Electrophiles (8)Diazo compounds (4)Azodicarboxylates (4)Cl-Electrophiles (chlorinating reagents) (3)F-Electrophiles (fluorinating reagents) (5)S-Electrophiles (thiolating reagents) (9)Info
| Molecule class | Nucleophiles » H-Nucleophiles » transition metal hydride donors |
| SMILES | |
| Quality |
 |
| Parameters |
N Param.: 1.60 sN Param.: 0.80 |
| Comment | Only 1 reference electrophile (Ar3C+) was used to determine N; sN was estimated (based on the sN of structurally related transition metal hydride donors). |
| Solvent | dichloromethane |
| Reference |
Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |