Mayr's Database of Reactivity Parameters

1,1-dimethyl-2-methylenehydrazine (in CH2Cl2)

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Hydrazines, Hydroxylamines etc.

Information panel

Name 1,1-dimethyl-2-methylenehydrazine (in CH2Cl2)
Structure
image of molecule
Molecule class Nucleophiles » N-Nucleophiles » Hydrazines, Hydroxylamines etc.
SMILES [H]/C([H])=N\N(C)C
Molecular formula C3H8N2
Quality ***
Parameters

N  Param.: 19.31

sN Param.: 0.46
Comment ambident nucleophile, C-reactivity: N = 6.98, sN = 0.85. Rate constants >108, close to diffusion control, were used to determine the reactivity parameters for N-attack. N and sN were determined with reference electrophiles.
Solvent dichloromethane
Reference Angew. Chem. Int. Ed. 2013, 52, 11900-11904
10.1002/anie.201305092