Mayr's Database of Reactivity Parameters

dibenzo[a,d]tropylium ion

Information panel

Name dibenzo[a,d]tropylium ion
Structure
Molecule class Electrophiles » C-Electrophiles » Carbocations » Other conjugated carbocations
SMILES C12=C(C=CC=C2)[CH+]C3=C(C=CC=C3)C=C1
Molecular formula C15H11
Quality -
Parameters

E Param.: -0.63

Comment

Revised E parameter calculated from rate constants of reactions with hydride donors (previously published E = -0.71). E parameter cannot be used to calculate rate constants for reactions with pi-nucleophiles (see original publication for details).

Solvent dichloromethane
Reference Liebigs Ann. 1995, , 2005-2009
10.1002/jlac.1995199[...]