Notice (8): session_start(): ps_files_cleanup_dir: opendir(/var/lib/php/sessions) failed: Permission denied (13) [APP/Controller/FeController.php, line 2]
Code Context
<?php
session_start();
session_start - [internal], line ??
include - APP/Controller/FeController.php, line 2
App::load() - CORE/Cake/Core/App.php, line 547
class_exists - [internal], line ??
Dispatcher::_loadController() - CORE/Cake/Routing/Dispatcher.php, line 266
Dispatcher::_getController() - CORE/Cake/Routing/Dispatcher.php, line 235
Dispatcher::dispatch() - CORE/Cake/Routing/Dispatcher.php, line 158
[main] - APP/webroot/index.php, line 107

Mayr's Database of Reactivity Parameters

• Advanced Search
• Nucleophiles (1292)
  • C-Nucleophiles (562)
    • Alkenes (57)
      • Mono-enes (44)
      • 1,3-Dienes (13)
    • Alkyl, Alkenyl and Aryl Boron Compounds (38)
      • Alkylating Boron Compounds (10)
      • Alkenylating Boron Compounds (1)
      • Arylating Boron Compounds (27)
    • Alkynes (1)
    • Allyl Element Compounds (38)
      • Allyl-B (5)
      • Allyl-Si (21)
      • Allyl-Sn, Ge, Zn or Fe (12)
    • Arenes (42)
      • Carbocyclic Arenes (6)
      • Indoles (18)
      • Pyrroles (7)
      • Other Heterocyclic Arenes (11)
    • Azolium enolates (4)
    • Breslow intermediates (11)
      • Desoxy-Breslow intermediates (7)
      • O-Methylated Breslow intermediates (4)
    • Carbanions (153)
      • Carbanions in DMSO (115)
      • Carbanions in water (17)
      • Carbanions in other solvents (21)
    • Carbenes (NHCs) (7)
    • Enol Ethers (51)
      • C=C-OR (4)
      • C=C-OSi (34)
      • C=C(OR)₂ (1)
      • C=C(OR)(OSi) (12)
    • Enamines, Enamides, and Ynamides (74)
    • Diazo Compounds and Hydrazones (20)
    • Isonitriles (5)
    • Metal-π-Complexes (5)
    • Metallocenes (6)
    • NHOs (conventional and mesoionic) (13)
    • Vinylsilanes (7)
    • Ylides (30)
      • Iodonium Ylides (4)
      • N-Ylides (9)
      • P-Ylides (7)
      • S-Ylides (10)
  • H-Nucleophiles (193)
    • H-B hydride donors (23)
    • H-C hydride donors (100)
    • H-Si hydride donors (39)
    • H-Sn and H-Ge hydride donors (5)
    • H-P hydride donors (6)
    • transition metal hydride donors (20)
  • Halide Anions (29)
  • O-Nucleophiles (138)
    • Alkoxide Anions (11)
    • Amide Anions (O reactivity)(0)
    • Alcohols and aqueous solvents (57)
      • Ethanol-Acetonitrile mixtures (8)
      • Methanol-Acetonitrile mixtures (8)
      • Other solvents (pure or mixtures) (11)
      • Water-Acetonitrile mixtures (8)
      • Water-Ethanol mixtures (7)
      • Water-HFIP mixtures (8)
      • Water-Trifluoroethanol mixtures (7)
    • Carboxylates and Carbonates (11)
    • Other O-centered nucleophiles (5)
    • Peroxy anions (16)
    • Phenolate Ions (38)
  • N-Nucleophiles (319)
    • Aliphatic amines (104)
    • Aromatic amines (7)
    • Amide anions (N reactivity) (21)
    • Amidines and Imines (10)
    • Amino acids (20)
    • Azoles and Azole Anions (33)
    • Guanidines (8)
    • Hydrazines, Hydroxylamines etc. (21)
    • Imidazolines and related compounds (10)
    • Isothioureas (12)
    • Nucleobases and Their Subunits (15)
    • Pyridines, Quinolines etc. (48)
    • Other N-centered nucleophiles (10)
  • S- and Se-Nucleophiles (33)
  • P-Nucleophiles (18)
• Electrophiles (355)
  • C-Electrophiles (330)
    • Carbocations (132)
      • Diarylcarbenium Ions (33)
      • Triarylcarbenium Ions (25)
      • Indolyl-stabilized carbocations (12)
      • Other conjugated carbocations (23)
      • N-substituted carbocations (iminium ions) (31)
      • O-substituted carbocations (carboxonium ions) (5)
      • S-substituted carbocations (3)
    • Cationic Metal-π-Complexes (20)
      • Fe-stabilized carbocations (9)
      • Co-stabilized carbocations (5)
      • Other metal-stabilized carbocations (6)
    • Acceptor-Substituted Ethylenes (117)
      • Acyl azolium ions (6)
      • Baylis-Hillman adducts (7)
      • Benzylidenemalonates (9)
      • Bissulfonyl ethylenes (7)
      • 1,2-Diaza-1,3-dienes (6)
      • Quinone Methides (19)
      • trans-β-Nitrostyrenes (6)
      • Other Michael acceptors (57)
    • Arenes (electron-deficient) (16)
    • Aldehydes (11)
    • Heteroallenes (X=C=Y) (6)
    • Imines (5)
    • Ketones (10)
    • Quinones (10)
    • CF3 transfer reagents (3)
  • N-Electrophiles (8)
    • Diazo compounds (4)
    • Diazonium ions(0)
    • Azodicarboxylates (4)
  • Cl-Electrophiles (chlorinating reagents) (3)
  • F-Electrophiles (fluorinating reagents) (5)
  • S-Electrophiles (thiolating reagents) (9)

• Info

  • About the database
  • Search Function
  • Further reading
  • Reactivity Scales Posters
  • Contact
  • Acknowledgement

1,3-dimethyl-2-methylene-2,3-dihydro-1H-benzo[d]imidazole

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » NHOs (conventional and mesoionic)

Information panel

Name	1,3-dimethyl-2-methylene-2,3-dihydro-1H-benzo[d]imidazole
Structure
Molecule class	Nucleophiles » C-Nucleophiles » NHOs (conventional and mesoionic)
SMILES	C=C1N(C)C(C=CC=C2)=C2N1C
Molecular formula	C10H12N2
Quality
Parameters	N  Param.: 19.84 sN Param.: 0.58
Solvent	THF
Reference	J. Org. Chem. 2021, 86, 2974-2985 10.1021/acs.joc.0c02838