Mayr's Database of Reactivity Parameters

chloro(phenylsulfonyl)methanide (in DMF)

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Name chloro(phenylsulfonyl)methanide (in DMF)
Structure
Molecule class Nucleophiles » C-Nucleophiles » Carbanions » Carbanions in other solvents
SMILES Cl[CH-]S(=O)(C1=CC=CC=C1)=O
Molecular formula C7H6ClO2S
Quality -
Parameters

N  Param.: 26.64

sN Param.: 0.64
Comment Kinetics of reactions with arylidenemalonates at -40°C converted to 20°C by using an activation entropy of -111 J/(mol K).
Solvent DMF
Reference Chem. Eur. J. 2008, 14, 6108-6118
10.1002/chem.200800329