Mayr's Database of Reactivity Parameters

dimethyl diazomalonate

Information panel

Name dimethyl diazomalonate
Structure
Molecule class Electrophiles » N-Electrophiles » Diazo compounds
SMILES O=C(C(C(OC)=O)=[N+]=[N-])OC
Molecular formula C5H6N2O4
Quality ***
Parameters

E Param.: -18.20

Comment

E was determined with reference nucleophiles (enamines in CDCl3) and sulfonium ylides (in DMSO).

Reference Chem. Eur. J. 2022, 28, e202201376
10.1002/chem.202201376