8-(benzyloxy)-2,2-di-tert-butyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3,2]dioxasiline
Information panel
| Name | 8-(benzyloxy)-2,2-di-tert-butyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3,2]dioxasiline |
| Structure |
|
| Molecule class | Nucleophiles » C-Nucleophiles » Enol Ethers » C=C-OR |
| SMILES | CC([Si](O1)(C(C)(C)C)OC[C@@H]2[C@@H]1[C@H](OCC3=CC=CC=C3)C=CO2)(C)C |
| Molecular formula | C21H32O4Si |
| Quality |
 |
| Parameters |
N Param.: 1.85 sN Param.: 1.28 |
| Comment |
Diarylmethylium (benzhydrylium) and indolyl-aryl-methylium ions were used for the nucleophilicity determination. |
| Solvent | dichloromethane |
| Reference |
Angew. Chem. Int. Ed. 2026, EarlyView, e24329 10.1002/anie.202524329 |