Mayr's Database of Reactivity Parameters

thiocyanate (in MeCN)

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Other N-centered nucleophiles

Information panel

Name thiocyanate (in MeCN)
Structure
image of molecule
Molecule class Nucleophiles » N-Nucleophiles » Other N-centered nucleophiles
SMILES [S-]C#N
Molecular formula CNS
Quality *
Parameters

N  Param.: 12.13

sN Param.: 0.60
Comment

Ambident nucleophile, S reactivity: N = 17.94, sN = 0.60. N was determined with reference electrophiles, however sN was estimated to be identical as for the S-attack.
Solvent MeCN
Reference J. Am. Chem. Soc. 2003, 125, 14126-14132
10.1021/ja037317u