Mayr's Database of Reactivity Parameters

(E)-4,4-dimethyl-1-(4-nitrophenyl)pent-1-en-3-one

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles » Acceptor-Substituted Ethylenes » Other Michael acceptors

Information panel

Name (E)-4,4-dimethyl-1-(4-nitrophenyl)pent-1-en-3-one
Structure
image of molecule
Molecule class Electrophiles » C-Electrophiles » Acceptor-Substituted Ethylenes » Other Michael acceptors
SMILES
Molecular formula C13H15NO3
Quality *
Parameters

E Param.: -19.15
Comment Only 1 reference nucleophile was used to determine the E parameter. Determined from a cyclopropanation reaction with an S-ylide.
Solvent DMSO
Reference J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m