3-chloro-benzaldehyde (in DMSO)
Information panel
| Name | 3-chloro-benzaldehyde (in DMSO) |
| Structure |
|
| Molecule class | Electrophiles » C-Electrophiles » Aldehydes |
| SMILES | [H]C(C1=CC(Cl)=CC=C1)=O |
| Molecular formula | C7H5ClO |
| Quality |
 |
| Parameters | |
| Comment |
The previously reported E = -18.0 holds for the gross rate constant of the reversible attack of the S-ylide (4-NC-C6H4)CH=SMe2 at ArCHO (epoxide ring closure is rate-determining). |
| Solvent | DMSO |
| Reference |
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |