Mayr's Database of Reactivity Parameters

3-fluoro-benzaldehyde (in DMSO)

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Name 3-fluoro-benzaldehyde (in DMSO)
Structure
Molecule class Electrophiles » C-Electrophiles » Aldehydes
SMILES [H]C(C1=CC(F)=CC=C1)=O
Molecular formula C7H5FO
Quality -
Parameters
Comment The reported E = ľ18.27 holds for the gross rate constant of the reversible attack of the S-ylide (4-NC-C6H4)CH=SMe2 at ArCHO (rate-determining epoxide ring closure).
Solvent DMSO
Reference J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m