4-fluoro-benzaldehyde (in DMSO)
Information panel
Name | 4-fluoro-benzaldehyde (in DMSO) |
Structure | |
Molecule class | Electrophiles » C-Electrophiles » Aldehydes |
SMILES | [H]C(C1=CC=C(F)C=C1)=O |
Molecular formula | C7H5FO |
Quality | |
Parameters | |
Comment | The reported E = –19.42 holds for the gross rate constant of the reversible attack of the S-ylide (4-NC-C6H4)CH=SMe2 at ArCHO (rate-determining epoxide ring closure). |
Solvent | DMSO |
Reference |
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |