p-nitro-cinnamaldehyde (in DMSO)
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| Name | p-nitro-cinnamaldehyde (in DMSO) |
| Structure |
|
| Molecule class | Electrophiles » C-Electrophiles » Aldehydes |
| SMILES | O=CC=Cc1ccc(N(=O)=O)cc1 |
| Molecular formula | C9H7NO3 |
| Quality |
 |
| Parameters | |
| Comment | The reported E = –18.19 holds for the gross rate constant of the reversible attack of the S-ylide (4-NC-C6H4)CH=SMe2 at ArCHO (rate-determining epoxide ring closure). |
| Solvent | DMSO |
| Reference |
J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |