Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
methionine (anionic, in water)	water	N Param.: 13.16 s_N Param.: 0.58	Org. Biomol. Chem. 2007, 5, 3814-3820 10.1039/b713778h
methanolate (in methanol)	MeOH	N Param.: 15.78 s_N Param.: 0.56	Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170
methanolate (in 91M9AN)	MeOH-MeCN mix	N Param.: 14.51 s_N Param.: 0.68	Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170
methanol (in MeCN)	MeCN	N Param.: 6.86 s_N Param.: 0.73	Bull. Chem. Soc. Jpn. 2018, 91, 523-530 10.1246/bcsj.20170360
methanol	MeOH	N Param.: 7.54 s_N Param.: 0.92	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
methanesulfonamide anion (in DMSO)	DMSO	N Param.: 18.61 s_N Param.: 0.53	J. Org. Chem. 2010, 75, 5250-5258 10.1021/jo1009883
MeSO2-CH-CO2Et (in DMSO)	DMSO	N Param.: 18.00 s_N Param.: 0.66	Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455
MeSO-CH-CO2Et (in DMSO)	DMSO	N Param.: 20.61 s_N Param.: 0.64	Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455
MeO-Breslow 1e	THF	N Param.: 15.65 s_N Param.: 0.52	Angew. Chem. Int. Ed. 2012, 51, 10408-10412 10.1002/anie.201204524
MeO-Breslow 1c	THF	N Param.: 16.61 s_N Param.: 0.68	Angew. Chem. Int. Ed. 2012, 51, 10408-10412 10.1002/anie.201204524
MeO-Breslow 1b	THF	N Param.: 10.45 s_N Param.: 0.81	Angew. Chem. Int. Ed. 2012, 51, 10408-10412 10.1002/anie.201204524
MeO-Breslow 1a	THF	N Param.: 14.77 s_N Param.: 0.80	Angew. Chem. Int. Ed. 2012, 51, 10408-10412 10.1002/anie.201204524
Meldrum's acid iodonium ylide (in CH2Cl2)	dichloromethane	N Param.: 4.36 s_N Param.: 1.06	J. Am. Chem. Soc. 2016, 138, 10304-10313 10.1021/jacs.6b05768
Me2S=CH-CO2Et (in DMSO)	DMSO	N Param.: 15.85 s_N Param.: 0.61	Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455
Me2S=CH-CN (in DMSO)	DMSO	N Param.: 16.23 s_N Param.: 0.60	Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455
Me2S=CH(p-NO2-C6H4) (in DMSO)	DMSO	N Param.: 18.42 s_N Param.: 0.65	J. Am. Chem. Soc. 2010, 132, 17894-17900 10.1021/ja1084749
Me2S=CH(4-CN-C6H4) (in DMSO)	DMSO	N Param.: 21.07 s_N Param.: 0.68	J. Am. Chem. Soc. 2010, 132, 17894-17900 10.1021/ja1084749
Me2S(O)=CH2 (in DMSO)	DMSO	N Param.: 21.29 s_N Param.: 0.47	J. Am. Chem. Soc. 2010, 132, 17894-17900 10.1021/ja1084749
Me2 Imd boronate	dichloromethane	N Param.: 11.88 s_N Param.: 0.71	Org. Lett. 2012, 14, 82-85 10.1021/ol202836p
maleimide anion (in DMSO)	DMSO	N Param.: 14.87 s_N Param.: 0.76	J. Org. Chem. 2010, 75, 5250-5258 10.1021/jo1009883