Mayr's Database of Reactivity Parameters

Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
tricyclohexylphosphane
C18H33P *
dichloromethane

N  Param.: 14.64

sN Param.: 0.68
*** Chem. Eur. J. 2005, 11, 917-927
10.1002/chem.200400696
tri-n-butylphosphane
C12H27P *
dichloromethane

N  Param.: 15.49

sN Param.: 0.69
*** Chem. Eur. J. 2005, 11, 917-927
10.1002/chem.200400696
triphenyl phosphite
C18H15O3P *
dichloromethane

N  Param.: 5.51

sN Param.: 0.76
*** Chem. Eur. J. 2005, 11, 917-927
10.1002/chem.200400696
tributyl phosphite
C12H27O3P *
dichloromethane

N  Param.: 10.36

sN Param.: 0.70
*** Chem. Eur. J. 2005, 11, 917-927
10.1002/chem.200400696
anion of nitroethane (in DMSO)
C2H4NO2 *
DMSO

N  Param.: 21.54

sN Param.: 0.62
*** J. Org. Chem. 2003, 68, 6880-6886
10.1021/jo0344182
cyclohexa-1,3-diene
C6H8 *
dichloromethane

N  Param.: 0.67

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
cyclohepta-1,3-diene
C7H10 *
dichloromethane

N  Param.: 0.06

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
cycloocta-1,3-diene
C8H12 *
dichloromethane

N  Param.: -0.50

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
cyclopentadiene
C5H6 *
dichloromethane

N  Param.: 2.30

sN Param.: 1.06
*** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
3,3-dimethyl-2-(trimethylsiloxy)buten
C9H20OSi *
dichloromethane

N  Param.: 3.78

sN Param.: 0.79
** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y