Mayr's Database of Reactivity Parameters

C-Nucleophiles

14 | 15 | 16 | 17 | 18 | 19 | 20 | 21 | 22 Found 572 molecules, displaying page 18 of 29 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
1,1-dimethyl-2-methylenehydrazine (in CH2Cl2)
C3H8N2*
dichloromethane

N  Param.: 6.98

sN Param.: 0.85
***Angew. Chem. Int. Ed. 2013, 52, 11900-11904
10.1002/anie.201305092
lithium (5-methylthiophen-2-yl)(4-methylphenyl)pinacolborate
C18H24BLiO2S*
MeCN

N  Param.: 6.98

sN Param.: 0.93
**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
2-methylindole
C9H9N*
MeCN

N  Param.: 6.91

sN Param.: 1.10
*J. Org. Chem. 2006, 71, 9088-9095
10.1021/jo0614339
Dimethyl bis(indenyl)zirconium(IV)
*
dichloromethane

N  Param.: 6.89

sN Param.: 1.00
*Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
potassium trifluoro(furan-3-yl)borate
C4H3BF3KO*
MeCN

N  Param.: 6.83

sN Param.: 0.93
***J. Am. Chem. Soc. 2013, 135, 6317-6324
10.1021/ja4017655
(allyl)dicarbonyl(cyclopentadienyl)iron(II)
*
dichloromethane

N  Param.: 6.78

sN Param.: 0.95
***Helv. Chim. Acta 2005, 88, 1754-1768
10.1002/hlca.200590137
1-(trimethylsiloxy)cyclooctene
C11H22OSi*
dichloromethane

N  Param.: 6.77

sN Param.: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
lithium (5-methylthiophen-2-yl)(4-chlorophenyl)pinacolborate
C17H21BClLiO2S*
MeCN

N  Param.: 6.77

sN Param.: 0.88
**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
6-(4-dimethylamino-phenyl)fulvene
C14H15N*
MeCN

N  Param.: 6.72

sN Param.: 0.87
***Eur. J. Org. Chem. 2009, , 1202-1206
10.1002/ejoc.200801099
(1H-inden-1-yl)trimethylstannane (in CH2Cl2)
C12H16Sn*
dichloromethane

N  Param.: 6.68

sN Param.: 0.81
***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
10.1002/anie.201501385
azulene
C10H8*
MeCN

N  Param.: 6.66

sN Param.: 1.02
***Eur. J. Org. Chem. 2009, , 1202-1206
10.1002/ejoc.200801099
lithium 2-isopropyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C16H23BF3LiO2*
MeCN

N  Param.: 6.63

sN Param.: 0.75
*Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
1-(trimethylsiloxy)cycloheptene
C10H20OSi*
dichloromethane

N  Param.: 6.62

sN Param.: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
1-(trimethylsiloxy)cyclopentene
C8H16OSi*
dichloromethane

N  Param.: 6.57

sN Param.: 0.93
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
N-(1-(p-tolyl)vinyl)acetamide
C11H13NO*
MeCN

N  Param.: 6.57

sN Param.: 0.91
**Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
1,2-dimethylindole
C10H11N*
dichloromethane

N  Param.: 6.54

sN Param.: 1.10
*J. Org. Chem. 2006, 71, 9088-9095
10.1021/jo0614339
lithium (5-methylthiophen-2-yl)(4-(trifluoromethyl)phenyl)catecholglycolborate
C18H13BF3LiO2S*
MeCN

N  Param.: 6.50

sN Param.: 0.77
**Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
(E)-2,2,3,5,5-pentamethyl-1-styrylimidazolidine-4-thione (in MeCN)
C16H22N2S*
MeCN

N  Param.: 6.49

sN Param.: 0.83
***Chem. Eur. J. 2024, 30, e202302764
10.1002/chem.202302764
potassium (1-(tert-butoxycarbonyl)-1H-indol-2-yl)trifluoroborate
C13H14BF3KNO2*
MeCN

N  Param.: 6.46

sN Param.: 0.96
***J. Am. Chem. Soc. 2013, 135, 6317-6324
10.1021/ja4017655
5-hydroxy-indole
C8H7NO*
MeCN

N  Param.: 6.44

sN Param.: 1.10
*J. Org. Chem. 2006, 71, 9088-9095
10.1021/jo0614339