C-Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
1,3-Bis(2,6-diisopropylphenyl)-5-(4-methoxyphenyl)-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Param.: 23.55 s_N Param.: 0.56	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
1,3-Bis(2,6-diisopropylphenyl)-5-methylene-4-(2,4,6-triisopropylphenyl)-4,5-dihydro-1H-1,2,3-triazol-3-ium-4-ide (in THF)	THF	N Param.: 20.78 s_N Param.: 0.61	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
1,3-Diisopropyl-4-methylene-5-phenyl-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Param.: 30.25 s_N Param.: 0.54	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
5-(tert-Butyl)-1,3-diisopropyl-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Param.: 31.92 s_N Param.: 0.52	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
1,3-bis(2,6-diisopropylphenyl)-4-methylene-5-phenyl-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Param.: 22.80 s_N Param.: 0.60	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
1,3-bis(2,6-diisopropylphenyl)-5-methyl-4-methylene-4,5-dihydro-1H-1,2,3-triazol-3-ium-5-ide (in THF)	THF	N Param.: 24.86 s_N Param.: 0.52	Angew. Chem. Int. Ed. 2023, 62, e202309790 10.1002/anie.202309790
diazocyclopentadiene (in CH2Cl2)	dichloromethane	N Param.: 4.84 s_N Param.: 1.06	Synthesis 2023, 55, 354-358 10.1055/s-0041-1737327
methyl diazoacetate	dichloromethane	N Param.: 4.68 s_N Param.: 0.94	J. Am. Chem. Soc. 2023, 145, 7416-7434 10.1021/jacs.2c13872
dimethyl diazomalonate	dichloromethane	N Param.: -1.24 s_N Param.: 0.81	J. Am. Chem. Soc. 2023, 145, 7416-7434 10.1021/jacs.2c13872
lithium 4,4,5,5-tetramethyl-2-phenyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolan-2-uide (in MeCN)	MeCN	N Param.: 11.00 s_N Param.: 0.57	J. Am. Chem. Soc. 2022, 144, 16118-16130 10.1021/jacs.2c06493
1,3-dimethyl-2-methyleneimidazolidine (in THF)	THF	N Param.: 18.11 s_N Param.: 0.68	J. Org. Chem. 2021, 86, 2974-2985 10.1021/acs.joc.0c02838
1,3-dimethyl-2-methylenehexahydropyrimidine (in THF)	THF	N Param.: 18.68 s_N Param.: 0.63	J. Org. Chem. 2021, 86, 2974-2985 10.1021/acs.joc.0c02838
1,3-dimesityl-2-methylene-2,3-dihydro-1H-imidazole (in THF)	THF	N Param.: 17.80 s_N Param.: 0.79	J. Org. Chem. 2021, 86, 2974-2985 10.1021/acs.joc.0c02838
1,3-dimethyl-2-methylene-2,3-dihydro-1H-benzo[d]imidazole	THF	N Param.: 19.84 s_N Param.: 0.58	J. Org. Chem. 2021, 86, 2974-2985 10.1021/acs.joc.0c02838
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in MeCN)	MeCN	N Param.: 16.15 s_N Param.: 0.99	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
anion of 4-cyanobenzyl trifluoromethyl sulfone (in MeCN)	MeCN	N Param.: 15.62 s_N Param.: 0.99	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
anion of 4-nitrobenzyl-CN (in MeCN)	MeCN	N Param.: 20.10 s_N Param.: 0.71	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
anion of (4-NO2-C6H4)CH2SO2Ph (in MeCN)	MeCN	N Param.: 19.90 s_N Param.: 0.66	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
1-((diphenylmethylene)amino)-2-ethoxy-2-oxoethan-1-ide (in DMSO)	DMSO	N Param.: 26.95 s_N Param.: 0.52	Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...]
2-(tert-butoxy)-1-((diphenylmethylene)amino)-2-oxoethan-1-ide (in DMSO)	DMSO	N Param.: 27.77 s_N Param.: 0.47	Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...]