C-Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
1-pyrrolidino-3,4-dihydronaphthalene (in MeCN)	MeCN	N Param.: 14.09 s_N Param.: 0.66	Synthesis 2019, 51, 1157-1170 10.1055/s-0037-1611634
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in MeCN)	MeCN	N Param.: 16.15 s_N Param.: 0.99	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
anion of 4-cyanobenzyl trifluoromethyl sulfone (in MeCN)	MeCN	N Param.: 15.62 s_N Param.: 0.99	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
anion of 4-nitrobenzyl-CN (in MeCN)	MeCN	N Param.: 20.10 s_N Param.: 0.71	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
anion of (4-NO2-C6H4)CH2SO2Ph (in MeCN)	MeCN	N Param.: 19.90 s_N Param.: 0.66	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
1,3-dimethyl-2-methyleneimidazolidine (in THF)	THF	N Param.: 18.11 s_N Param.: 0.68	J. Org. Chem. 2021, 86, 2974-2985 10.1021/acs.joc.0c02838
1,3-dimethyl-2-methylenehexahydropyrimidine (in THF)	THF	N Param.: 18.68 s_N Param.: 0.63	J. Org. Chem. 2021, 86, 2974-2985 10.1021/acs.joc.0c02838
1,3-dimesityl-2-methylene-2,3-dihydro-1H-imidazole (in THF)	THF	N Param.: 17.80 s_N Param.: 0.79	J. Org. Chem. 2021, 86, 2974-2985 10.1021/acs.joc.0c02838
1,3-dimethyl-2-methylene-2,3-dihydro-1H-benzo[d]imidazole	THF	N Param.: 19.84 s_N Param.: 0.58	J. Org. Chem. 2021, 86, 2974-2985 10.1021/acs.joc.0c02838
lithium 4,4,5,5-tetramethyl-2-phenyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolan-2-uide (in MeCN)	MeCN	N Param.: 11.00 s_N Param.: 0.57	J. Am. Chem. Soc. 2022, 144, 16118-16130 10.1021/jacs.2c06493