Mayr's Database of Reactivity Parameters

C-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
toluene
C7H8 *
 dichloromethane

N  Param.: -4.36

sN Param.: 1.77		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
m-xylene
C8H10 *
 dichloromethane

N  Param.: -3.57

sN Param.: 2.08		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(E)-propenylbenzene
C9H10 *
 dichloromethane

N  Param.: -0.49

sN Param.: 1.18		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2-methylthiophene
C5H6S *
 dichloromethane

N  Param.: 1.35

sN Param.: 0.99		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
styrene
C8H8 *
 dichloromethane

N  Param.: 0.78

sN Param.: 0.95		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1,3-dimethoxybenzene
C8H10O2 *
 dichloromethane

N  Param.: 2.48

sN Param.: 1.09		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
allyltrimethylsilane
C6H14Si *
 dichloromethane

N  Param.: 1.68

sN Param.: 1.00		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
allyltriphenylstannane
C21H20Sn *
 dichloromethane

N  Param.: 3.09

sN Param.: 0.90		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(2-methylallyl)trimethylsilane
C7H16Si *
 dichloromethane

N  Param.: 4.41

sN Param.: 0.96		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
allyltributylstannane
C15H32Sn *
 dichloromethane

N  Param.: 5.46

sN Param.: 0.89		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y