Mayr's Database of Reactivity Parameters

C-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles
4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 Found 572 molecules, displaying page 9 of 12 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
anion of diethyl 2-cyclohexylmalonate (in DMSO)
C13H21O4*
 DMSO

N  Param.: 19.23

sN Param.: 0.67		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of diethyl 2-phenylmalonate (in DMSO)
C13H15O4*
 DMSO

N  Param.: 15.93

sN Param.: 0.99		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of diethyl 2-(4-nitrophenyl)malonate (in DMSO)
C13H14NO6*
 DMSO

N  Param.: 14.94

sN Param.: 0.96		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of triethyl methanetricarboxylate (in DMSO)
C10H15O6*
 DMSO

N  Param.: 15.33

sN Param.: 0.72		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of diethyl 2-(acetyl)malonate (in DMSO)
C9H13O5*
 DMSO

N  Param.: 13.83

sN Param.: 0.84		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of diethyl 2-(benzoyl)malonate (in DMSO)
C14H15O5*
 DMSO

N  Param.: 13.63

sN Param.: 0.80		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of 5-phenyl Meldrum's acid (in DMSO)
C12H11O4*
 DMSO

N  Param.: 11.54

sN Param.: 0.95		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
anion of diethyl 2-(p-anisyl)malonate (in DMSO)
C14H17O5*
 DMSO

N  Param.: 16.73

sN Param.: 0.91		***Eur. J. Org. Chem. 2016, , 1841-1848
10.1002/ejoc.201600107
Cp2Zr(Me)2 - Dimethylzirconocene
*
 dichloromethane

N  Param.: 4.35

sN Param.: 1.09		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Cp2Zr(CH2Ph)2 - Dibenzylzirconocene
*
 dichloromethane

N  Param.: 5.10

sN Param.: 1.03		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
(Cp*)2Zr(Me)2 - Dimethyl-bis(pentamethylcyclopentadienyl)zirconium
C22H36Zr*
 dichloromethane

N  Param.: 5.49

sN Param.: 1.06		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
3-mesityl-1-methyl-1H-imidazol-3-ium-2-ide (in THF)
C13H16N2*
 THF

N  Param.: 21.50

sN Param.: 0.45		***Org. Lett. 2016, 18, 3566-3569
10.1021/acs.orglett.[...]
3-(tert-butyl)-1-methyl-1H-imidazol-3-ium-2-ide (in THF)
C8H14N2*
 THF

N  Param.: 16.54

sN Param.: 0.47		***Org. Lett. 2016, 18, 3566-3569
10.1021/acs.orglett.[...]
3-(4-methoxyphenyl)-1-methyl-1H-imidazol-3-ium-2-ide (in THF)
C11H12N2O*
 THF

N  Param.: 20.41

sN Param.: 0.46		***Org. Lett. 2016, 18, 3566-3569
10.1021/acs.orglett.[...]
3-(2,6-dimethoxyphenyl)-1-methyl-1H-imidazol-3-ium-2-ide (in THF)
C12H14N2O2*
 THF

N  Param.: 23.00

sN Param.: 0.46		***Org. Lett. 2016, 18, 3566-3569
10.1021/acs.orglett.[...]
Meldrum's acid iodonium ylide (in CH2Cl2)
*
 dichloromethane

N  Param.: 4.36

sN Param.: 1.06		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
Dimedone iodonium ylide (in CH2Cl2)
*
 dichloromethane

N  Param.: 6.18

sN Param.: 0.81		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
N,N-Dimethylbarbituric acid iodonium ylide (in CHCl2)
*
 dichloromethane

N  Param.: 7.98

sN Param.: 0.71		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
6-methyl-3-(phenyl-l3-iodanylidene)dihydro-2H-pyran-2,4(3H)-dione (in CH2Cl2)
*
 dichloromethane

N  Param.: 4.67

sN Param.: 0.92		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
bis(phenylsulfonyl)methanide (in DMSO)
C13H11O4S2*
 DMSO

N  Param.: 15.68

sN Param.: 0.74		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
fluorobis(phenylsulfonyl)methanide (in DMSO)
C13H10FO4S2*
 DMSO

N  Param.: 17.46

sN Param.: 0.73		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
methoxybis(phenylsulfonyl)methanide (in DMSO)
C14H13O5S2*
 DMSO

N  Param.: 17.29

sN Param.: 0.70		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)
C7H5O4S2*
 DMSO

N  Param.: 16.06

sN Param.: 0.69		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-fluoro-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)
C7H4FO4S2*
 DMSO

N  Param.: 19.03

sN Param.: 0.58		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-methoxy-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)
C8H7O5S2*
 DMSO

N  Param.: 17.36

sN Param.: 0.71		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-ethoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)
C10H11O4S*
 DMSO

N  Param.: 18.81

sN Param.: 0.59		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-ethoxy-1-fluoro-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)
C10H10FO4S*
 DMSO

N  Param.: 20.51

sN Param.: 0.64		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-ethoxy-1-methoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)
C11H13O5S*
 DMSO

N  Param.: 19.15

sN Param.: 0.59		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
1,3-diethoxy-2-fluoro-1,3-dioxopropan-2-ide (in DMSO)
C7H10FO4*
 DMSO

N  Param.: 20.63

sN Param.: 0.76		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
2-chloro-1,3-diethoxy-1,3-dioxopropan-2-ide (in DMSO)
C7H10ClO4*
 DMSO

N  Param.: 18.19

sN Param.: 0.74		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
1,2,3-trimethoxy-1,3-dioxopropan-2-ide (in DMSO)
C6H9O5*
 DMSO

N  Param.: 20.08

sN Param.: 0.74		***Angew. Chem. Int. Ed. 2016, 55, 12845-12848
10.1002/anie.201605616
chloro(phenylsulfonyl)methanide (in DMSO)
C7H6ClO2S*
 DMSO

N  Param.: 28.27

sN Param.: 0.42		***J. Org. Chem. 2017, 82, 2011-2017
10.1021/acs.joc.6b02844
bromo(phenylsulfonyl)methanide (in DMSO)
C7H6BrO2S*
 DMSO

N  Param.: 23.90

sN Param.: 0.62		***J. Org. Chem. 2017, 82, 2011-2017
10.1021/acs.joc.6b02844
chloro((4-cyanophenyl)sulfonyl)methanide (in DMSO)
C8H5ClNO2S*
 DMSO

N  Param.: 25.59

sN Param.: 0.51		***J. Org. Chem. 2017, 82, 2011-2017
10.1021/acs.joc.6b02844
chloro((4-nitrophenyl)sulfonyl)methanide (in DMSO)
C7H5ClNO4S*
 DMSO

N  Param.: 24.88

sN Param.: 0.49		***J. Org. Chem. 2017, 82, 2011-2017
10.1021/acs.joc.6b02844
chloro((4-chlorophenyl)sulfonyl)methanide (in DMSO)
C7H5Cl2O2S*
 DMSO

N  Param.: 26.90

sN Param.: 0.45		***J. Org. Chem. 2017, 82, 2011-2017
10.1021/acs.joc.6b02844
anion of ethyl 2-cyano-2-phenylacetate (in DMSO)
C11H10NO2*
 DMSO

N  Param.: 15.85

sN Param.: 1.04		***Eur. J. Org. Chem. 2017, , 1196-1202
10.1002/ejoc.201601513
anion of 2-phenylmalononitrile (in DMSO)
C9H5N2*
 DMSO

N  Param.: 15.58

sN Param.: 1.00		***Eur. J. Org. Chem. 2017, , 1196-1202
10.1002/ejoc.201601513
anion of 2-phenyl-2-(phenylsulfonyl)acetonitrile (in DMSO)
C14H10NO2S*
 DMSO

N  Param.: 15.97

sN Param.: 0.72		***Eur. J. Org. Chem. 2017, , 1196-1202
10.1002/ejoc.201601513
anion of (phenylmethylenedisulfonyl)dibenzene (in DMSO)
C19H15O4S2*
 DMSO

N  Param.: 15.07

sN Param.: 0.79		***Eur. J. Org. Chem. 2017, , 1196-1202
10.1002/ejoc.201601513
anion of 1,2,3-triphenylpropane-1,3-dione (in DMSO)
C21H15O2*
 DMSO

N  Param.: 14.99

sN Param.: 0.83		***Eur. J. Org. Chem. 2017, , 1196-1202
10.1002/ejoc.201601513
barbiturate anion (in DMSO)
C4H3N2O3*
 DMSO

N  Param.: 15.59

sN Param.: 0.80		***J. Org. Chem. 2017, 82, 8476-8488
10.1021/acs.joc.7b01223
1,3-dimethylbarbiturate anion (in DMSO)
C6H7N2O3*
 DMSO

N  Param.: 17.46

sN Param.: 0.72		***J. Org. Chem. 2017, 82, 8476-8488
10.1021/acs.joc.7b01223
2-thiobarbiturate anion (in DMSO)
C4H3N2O2S*
 DMSO

N  Param.: 14.24

sN Param.: 0.82		***J. Org. Chem. 2017, 82, 8476-8488
10.1021/acs.joc.7b01223
1,3-diethyl-thiobarbiturate anion (in DMSO)
C8H11N2O2S*
 DMSO

N  Param.: 14.90

sN Param.: 0.80		***J. Org. Chem. 2017, 82, 8476-8488
10.1021/acs.joc.7b01223
4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane (in CH2Cl2)
C9H17BO2*
 dichloromethane

N  Param.: -0.64

sN Param.: 1.10		***J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
lithium 2-allyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)
C17H20BF6LiO2*
 MeCN

N  Param.: 8.71

sN Param.: 0.80		***J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
lithium (E)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(but-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)
C18H22BF6LiO2*
 MeCN

N  Param.: 9.49

sN Param.: 0.82		***J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
(E)-1-(2-(4-methoxyphenyl)-1-phenylvinyl)pyrrolidine (in MeCN)
*
 MeCN

N  Param.: 11.99

sN Param.: 0.84		***Chem. Eur. J. 2018, 24, 5901-5910
10.1002/chem.201705962
(E)-1-(1,2-diphenylvinyl)pyrrolidine (in MeCN)
*
 MeCN

N  Param.: 11.66

sN Param.: 0.82		***Chem. Eur. J. 2018, 24, 5901-5910
10.1002/chem.201705962