Mayr's Database of Reactivity Parameters

O-Methylated Breslow intermediates

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Breslow intermediates
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
MeO-Breslow 1a
*
 THF

N  Param.: 14.77

sN Param.: 0.80		***Angew. Chem. Int. Ed. 2012, 51, 10408-10412
10.1002/anie.201204524
MeO-Breslow 1b
*
 THF

N  Param.: 10.45

sN Param.: 0.81		***Angew. Chem. Int. Ed. 2012, 51, 10408-10412
10.1002/anie.201204524
MeO-Breslow 1c
*
 THF

N  Param.: 16.61

sN Param.: 0.68		***Angew. Chem. Int. Ed. 2012, 51, 10408-10412
10.1002/anie.201204524
MeO-Breslow 1e
*
 THF

N  Param.: 15.65

sN Param.: 0.52		***Angew. Chem. Int. Ed. 2012, 51, 10408-10412
10.1002/anie.201204524