Mayr's Database of Reactivity Parameters

C-Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
(E)-but-2-enyltrimethylsilane
C7H16Si *
dichloromethane

N  Param.: 1.94

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(2,3-dimethylbut-2-enyl)triethylsilane
C12H26Si *
dichloromethane

N  Param.: 3.15

sN Param.: 1.15
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,3,3-trimethyl-but-1-ene
C7H14 *
dichloromethane

N  Param.: 0.06

sN Param.: 1.07
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,3-dimethyl-but-1-ene
C6H12 *
dichloromethane

N  Param.: 0.65

sN Param.: 1.00
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,4,4-trimethyl-pent-1-ene
C8H16 *
dichloromethane

N  Param.: 0.79

sN Param.: 1.07
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2-methyl-but-1-ene
C5H10 *
dichloromethane

N  Param.: 1.00

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,4-dimethyl-penta-1,4-diene
C7H12 *
dichloromethane

N  Param.: 0.54

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,5-dimethyl-hexa-1,5-diene
C8H14 *
dichloromethane

N  Param.: 1.14

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,6-dimethyl-hepta-1,6-diene
C9H16 *
dichloromethane

N  Param.: 1.69

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,7-dimethylocta-1,7-diene
C10H18 *
dichloromethane

N  Param.: 1.58

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c