Mayr's Database of Reactivity Parameters

C-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1-(trimethylsiloxy)cyclopentene
C8H16OSi *
 dichloromethane

N  Param.: 6.57

sN Param.: 0.93		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-phenoxy-1-(trimethylsiloxy)ethene
C11H16O2Si *
 dichloromethane

N  Param.: 8.23

sN Param.: 0.81		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-(N-morpholino)cyclohexene
C10H17NO *
 dichloromethane

N  Param.: 11.40

sN Param.: 0.83		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-(N-piperidino)cyclohexene
C11H19N *
 dichloromethane

N  Param.: 13.36

sN Param.: 0.81		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(Z)-but-2-ene
C4H8 *
 dichloromethane

N  Param.: -2.44

sN Param.: 1.09		 ** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
allyltriphenylsilane
C21H20Si *
 dichloromethane

N  Param.: -0.13

sN Param.: 1.21		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
3-methylanisole
C8H10O *
 dichloromethane

N  Param.: 0.13

sN Param.: 1.27		 *** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
phenylacetylene
C8H6 *
 dichloromethane

N  Param.: -0.04

sN Param.: 0.77		 *** Angew. Chem. Int. Ed. 2014, 53, 4968-4971
10.1002/anie.201402055
(triisopropylsiloxy)ethene
C11H24OSi *
 dichloromethane

N  Param.: 3.44

sN Param.: 0.94		 ** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(2-methylallyl)triphenylsilane
C22H22Si *
 dichloromethane

N  Param.: 4.17

sN Param.: 0.79		 ** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y