Mayr's Database of Reactivity Parameters

Peroxy anions

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles » Peroxy anions

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
HOO- (in water)
HO2 *
 water

N  Param.: 15.40

sN Param.: 0.55		 *** J. Am. Chem. Soc. 2003, 125, 286-295
10.1021/ja021010y
t-butylperoxy anion (in H2O)
C4H9O2 *
 water

N  Param.: 14.29

sN Param.: 0.51		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
cumene peroxy anion (in H2O)
C9H11O2 *
 water

N  Param.: 13.92

sN Param.: 0.61		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
phthalimidoperoxyhexanoate (in H2O)
C14H20NO5 *
 water

N  Param.: 16.02

sN Param.: 0.54		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
2-phenylperoxyacetate (in H2O)
C8H7O3 *
 water

N  Param.: 15.63

sN Param.: 0.56		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
3,5-dichloroperoxybenzoate (in H2O)
C7H3Cl2O3 *
 water

N  Param.: 17.93

sN Param.: 0.50		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
magnesium 2-carboperoxybenzoate (in H2O)
C8H4O5 *
 water

N  Param.: 18.43

sN Param.: 0.46		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
3-chloroperoxybenzoate (in H2O)
C7H4ClO3 *
 water

N  Param.: 18.19

sN Param.: 0.47		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
4-fluoroperoxybenzoate (in H2O)
C7H4FO3 *
 water

N  Param.: 17.99

sN Param.: 0.47		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
4-nitroperoxybenzoate (in H2O)
C7H4NO5 *
 water

N  Param.: 17.43

sN Param.: 0.50		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
4-methoxyperoxybenzoate (in H2O)
C8H7O4 *
 water

N  Param.: 17.84

sN Param.: 0.46		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
3-chloro-4-methoxyperoxybenzoate (in H2O)
C8H6ClO4 *
 water

N  Param.: 18.56

sN Param.: 0.48		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
peroxybenzoate (in H2O)
C7H5O3 *
 water

N  Param.: 18.57

sN Param.: 0.43		 *** Angew. Chem. Int. Ed. 2017, 56, 13279-13282
10.1002/anie.201707086
beta-piperidinium-peroxypropionate
*
 water

N  Param.: 13.94

sN Param.: 0.62		 *** Eur. J. Org. Chem. 2018, , 6010-6017
10.1002/ejoc.201801158
peroxy-beta-alanate
*
 water

N  Param.: 14.07

sN Param.: 0.56		 *** Eur. J. Org. Chem. 2018, , 6010-6017
10.1002/ejoc.201801158
peroxy-GABA
*
 water

N  Param.: 14.33

sN Param.: 0.57		 *** Eur. J. Org. Chem. 2018, , 6010-6017
10.1002/ejoc.201801158