Mayr's Database of Reactivity Parameters

Allyl-B

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Allyl Element Compounds » Allyl-B

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane (in CH2Cl2)
C9H17BO2 *
 dichloromethane

N  Param.: -0.64

sN Param.: 1.10		 *** J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
potassium allyltrifluoroborate (in MeCN)
C3H5BF3K *
 MeCN

N  Param.: 5.29

sN Param.: 0.87		 ** J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
lithium 2-allyl-2-(3,5-bis(trifluoromethyl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)
C17H20BF6LiO2 *
 MeCN

N  Param.: 8.71

sN Param.: 0.80		 *** J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
lithium 2-allyl-4,4,5,5-tetramethyl-2-phenyl-1,3,2-dioxaborolan-2-uide (in MeCN)
C15H22BLiO2 *
 MeCN

N  Param.: 11.20

sN Param.: 0.64		 * J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
lithium (E)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(but-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-uide (in MeCN)
C18H22BF6LiO2 *
 MeCN

N  Param.: 9.49

sN Param.: 0.82		 *** J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240