Mayr's Database of Reactivity Parameters

H-P hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles
« Back Forward » Found 6 molecules, displaying page 1 of 1 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C10H21N2P*
 MeCN

N  Param.: 25.54

sN Param.: 0.35		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-2,3-dihydro-1H-benzo[d][1,3,2]diazaphosphole (in MeCN)
C14H23N2P*
 MeCN

N  Param.: 20.93

sN Param.: 0.43		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C26H37N2P*
 MeCN

N  Param.: 19.85

sN Param.: 0.34		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-1,3,2-diazaphosphinane (in MeCN)
C11H25N2P*
 MeCN

N  Param.: 13.46

sN Param.: 0.52		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-1,3,2-diazaphospholidine (in MeCN)
C10H23N2P*
 MeCN

N  Param.: 18.74

sN Param.: 0.47		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-dimesityl-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C20H25N2P*
 MeCN

N  Param.: 17.68

sN Param.: 0.68		***Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456