Mayr's Database of Reactivity Parameters

H-P hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-P hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C10H21N2P *
 MeCN

N  Param.: 25.54

sN Param.: 0.35		 *** Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-2,3-dihydro-1H-benzo[d][1,3,2]diazaphosphole (in MeCN)
C14H23N2P *
 MeCN

N  Param.: 20.93

sN Param.: 0.43		 *** Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C26H37N2P *
 MeCN

N  Param.: 19.85

sN Param.: 0.34		 *** Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-1,3,2-diazaphosphinane (in MeCN)
C11H25N2P *
 MeCN

N  Param.: 13.46

sN Param.: 0.52		 *** Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-1,3,2-diazaphospholidine (in MeCN)
C10H23N2P *
 MeCN

N  Param.: 18.74

sN Param.: 0.47		 *** Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-dimesityl-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C20H25N2P *
 MeCN

N  Param.: 17.68

sN Param.: 0.68		 *** Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456