Mayr's Database of Reactivity Parameters

C=C-OSi

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Enol Ethers » C=C-OSi

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1-(trimethylsiloxy)cyclopentene (in MeCN)
C8H16OSi *
 MeCN

N  Param.: 6.43

sN Param.: 0.89		 *** Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046
(Z)-1,2-diphenyl-1-(trimethylsiloxy)ethene (in MeCN)
C17H20OSi *
 MeCN

N  Param.: 3.00

sN Param.: 0.83		 *** Synthesis 2019, 51, 1157-1170
10.1055/s-0037-1611634
(Z)-1-phenyl-1-(trimethylsiloxy)propene (in MeCN)
C12H18OSi *
 MeCN

N  Param.: 5.18

sN Param.: 0.94		 *** Synthesis 2019, 51, 1157-1170
10.1055/s-0037-1611634
3-(trimethylsiloxy)-1H-indene (in MeCN)
C12H16OSi *
 MeCN

N  Param.: 7.32

sN Param.: 0.82		 *** Synthesis 2019, 51, 1157-1170
10.1055/s-0037-1611634
1-(trimethylsiloxy)-3,4-dihydronaphthalene (in MeCN)
C13H18OSi *
 MeCN

N  Param.: 5.06

sN Param.: 0.91		 *** Synthesis 2019, 51, 1157-1170
10.1055/s-0037-1611634