Mayr's Database of Reactivity Parameters

Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
(2-methylallyl)tributylstannane
C16H34Sn *
 dichloromethane

N  Param.: 7.48

sN Param.: 0.89		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
Danishefskys diene
C8H16O2Si *
 dichloromethane

N  Param.: 8.57

sN Param.: 0.84		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-(trimethylsiloxy)-5,6-dihydro-4H-pyran
C8H16O2Si *
 dichloromethane

N  Param.: 10.61

sN Param.: 0.86		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
5-(trimethylsiloxy)-2,3-dihydrofuran
C7H14O2Si *
 dichloromethane

N  Param.: 12.56

sN Param.: 0.70		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
methylenecyclopentane
C6H10 *
 dichloromethane

N  Param.: 2.82

sN Param.: 0.90		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-methylfuran
C5H6O *
 dichloromethane

N  Param.: 3.61

sN Param.: 1.11		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
N-methylpyrrole
C5H7N *
 dichloromethane

N  Param.: 5.85

sN Param.: 1.03		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-(trimethylsiloxy)cyclohexene
C9H18OSi *
 dichloromethane

N  Param.: 5.21

sN Param.: 1.00		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-(trimethylsiloxy)propene
C6H14OSi *
 dichloromethane

N  Param.: 5.41

sN Param.: 0.91		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-phenyl-1-(trimethylsiloxy)ethene
C11H16OSi *
 dichloromethane

N  Param.: 6.22

sN Param.: 0.96		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y