Mayr's Database of Reactivity Parameters

Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
N-methyl-pyrrolidine (in CH2Cl2)
*
 dichloromethane

N  Param.: 20.60

sN Param.: 0.52		 * J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
N-methyl-piperidine (in MeCN)
*
 MeCN

N  Param.: 18.72

sN Param.: 0.52		 *** J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
N-methyl-piperidine (in CH2Cl2)
*
 dichloromethane

N  Param.: 18.90

sN Param.: 0.52		 * J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
N-methyl-morpholine (in MeCN)
*
 MeCN

N  Param.: 16.80

sN Param.: 0.52		 * J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
N-methyl-morpholine (in CH2Cl2)
*
 dichloromethane

N  Param.: 16.50

sN Param.: 0.52		 * J. Phys. Org. Chem. 2010, 23, 1029-1035
10.1002/poc.1707
phenylsulfinate (in DMSO)
*
 DMSO

N  Param.: 19.60

sN Param.: 0.60		 *** J. Am. Chem. Soc. 2010, 132, 4796-4805
10.1021/ja9102056
phenylsulfinate (in MeCN)
*
 MeCN

N  Param.: 20.11

sN Param.: 0.59		 *** J. Am. Chem. Soc. 2010, 132, 4796-4805
10.1021/ja9102056
phenylsulfinate (in 50W50AN)
*
 water-MeCN mix

N  Param.: 13.75

sN Param.: 0.68		 *** J. Am. Chem. Soc. 2010, 132, 4796-4805
10.1021/ja9102056
phthalimide anion (in DMSO)
*
 DMSO

N  Param.: 15.52

sN Param.: 0.67		 *** J. Org. Chem. 2010, 75, 5250-5258
10.1021/jo1009883
succinimide anion (in DMSO)
*
 DMSO

N  Param.: 16.03

sN Param.: 0.66		 *** J. Org. Chem. 2010, 75, 5250-5258
10.1021/jo1009883