Mayr's Database of Reactivity Parameters

Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
2-Et super-dmap (in MeCN)
*
 MeCN

N  Param.: 16.81

sN Param.: 0.60		 *** Org. Lett. 2011, 13, 530-533
10.1021/ol1029589
2-Bn super-dmap (in MeCN)
*
 MeCN

N  Param.: 17.69

sN Param.: 0.57		 *** Org. Lett. 2011, 13, 530-533
10.1021/ol1029589
2-Ac super-dmap (in MeCN)
*
 MeCN

N  Param.: 15.39

sN Param.: 0.60		 *** Org. Lett. 2011, 13, 530-533
10.1021/ol1029589
2-Bz super-dmap (in MeCN)
*
 MeCN

N  Param.: 14.19

sN Param.: 0.67		 *** Org. Lett. 2011, 13, 530-533
10.1021/ol1029589
acetate (in MeCN)
*
 MeCN

N  Param.: 16.90

sN Param.: 0.75		 *** J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
acetate (in 90A10W)
*
 aq acetone

N  Param.: 12.71

sN Param.: 0.68		 *** J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
acetate (in 80A20W)
*
 aq acetone

N  Param.: 12.50

sN Param.: 0.60		 ** J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
benzoate (in MeCN)
*
 MeCN

N  Param.: 16.82

sN Param.: 0.70		 *** J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
benzoate (in 90AN10W)
*
 aq MeCN

N  Param.: 11.30

sN Param.: 0.72		 ** J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
p-nitrobenzoate (in MeCN)
*
 MeCN

N  Param.: 15.30

sN Param.: 0.76		 *** J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464