Electrophiles
Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
---|---|---|---|---|
jul Meldrum's acid | E Param.: -13.97 | J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s | ||
diethyl benzylidene malonate | E Param.: -20.55 | Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 | ||
diethyl 4-nitrobenzylidene malonate | E Param.: -17.67 | Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 | ||
diethyl 4-cyano-benzylidene malonate | E Param.: -18.06 | Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 | ||
diethyl 3-chloro-benzylidene malonate | E Param.: -18.98 | Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 | ||
diethyl 4-methyl-benzylidene malonate | E Param.: -21.11 | Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 | ||
diethyl 4-methoxy-benzylidene malonate | E Param.: -21.47 | Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 | ||
diethyl 4-(dimethylamino)benzylidene malonate | E Param.: -23.10 | Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 | ||
diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate | E Param.: -23.40 | Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 | ||
diethyl 2-((julolidine-9-yl)methylene)malonate | E Param.: -23.80 | Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 | ||
Me2N+=CH-CH-Ph | E Param.: -9.20 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | ||
pyrN+=CH-CH-Ph | E Param.: -9.80 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | ||
pipN+=CH-CH-Ph | E Param.: -10.30 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | ||
(PhCH2)2N+=CH-CH-Ph | E Param.: -8.50 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | ||
Jorgensen/Hayashi-iminium ion | E Param.: -8.20 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | ||
MacMillan-iminium ion (1st generation) | MeCN | E Param.: -7.37 | Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683 | |
mor iminium | E Param.: -8.60 | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | ||
2,6-diphenyl-4-benzylidenecyclohexa-2,5-dienone | E Param.: -11.87 | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | ||
2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone | E Param.: -16.38 | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | ||
2,6-dimethoxy-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone | E Param.: -17.18 | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | ||
2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone | E Param.: -16.36 | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | ||
2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone | E Param.: -15.03 | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | ||
2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone | E Param.: -14.50 | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | ||
2,6-di-tert.butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-dienone | E Param.: -14.36 | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | ||
bh6a | E Param.: -18.60 | Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 | ||
bh 6f | E Param.: -18.90 | Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 | ||
bh 6i | E Param.: -19.10 | Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 | ||
bh6j | E Param.: -17.90 | Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 | ||
bh 6k | E Param.: -18.20 | Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 | ||
bh 6l | E Param.: -18.90 | Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 | ||
bh 6m | E Param.: -17.30 | Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 | ||
cumyl cation | E Param.: 5.74 | Macromolecules 2010, 43, 1719-1723 10.1021/ma9024569 | ||
1,2-diaza-1,3-diene 1a | DMSO | E Param.: -13.28 | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 | |
1,2-diaza-1,3-diene 1b | DMSO | E Param.: -13.90 | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 | |
1,2-diaza-1,3-diene 1c | DMSO | E Param.: -14.91 | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 | |
1,2-diaza-1,3-diene 1d | DMSO | E Param.: -15.38 | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 | |
1,2-diaza-1,3-diene 1e | MeOH | E Param.: -14.90 | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 | |
1,2-diaza-1,3-diene 1f | MeOH | E Param.: -15.30 | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 | |
2,3,4,5,6,6-hexachlorocyclohexa-2,4-dien-1-one | MeCN | E Param.: -6.75 | Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j | |
5,7,7-trichloro-8(7H)-quinolinone | MeCN | E Param.: -10.48 | Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j | |
2,2,4-trichloro-1(2H)-naphthalenone | MeCN | E Param.: -11.24 | Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j | |
dibenzyl azodicarboxylate | MeCN | E Param.: -8.89 | Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 | |
diethyl azodicarboxylate | MeCN | E Param.: -10.15 | Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 | |
diisopropyl azodicarboxylate | MeCN | E Param.: -10.71 | Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 | |
di-tert-butyl azodicarboxylate | MeCN | E Param.: -12.23 | Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 | |
(4-CF3)2-tritylium ion | E Param.: 2.28 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(3-Cl)3-tritylium ion | E Param.: 1.99 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-CF3)-tritylium ion | E Param.: 1.33 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(3-Cl)-tritylium ion | E Param.: 1.06 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(3-CF3)-tritylium ion | E Param.: 1.18 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-Me)-tritylium ion | E Param.: -0.13 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-Me)2-tritylium ion | E Param.: -0.70 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-Me)3-tritylium ion | E Param.: -1.21 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-MeO,3-OMe)-tritylium ion | E Param.: -1.62 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-OMe,3-Me)-tritylium ion | E Param.: -1.84 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-MeO)-tritylium ion | E Param.: -1.59 | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | ||
(4-MeO,4-Me)-tritylium ion | E Param.: -2.13 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-MeO)2-tritylium ion | E Param.: -3.04 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-MeO)3-tritylium ion | E Param.: -4.35 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-NMe2)-tritylium ion | E Param.: -7.93 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-NMe2)2-tritylium ion (= Malachite green) | E Param.: -10.29 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(4-NMe2)3-tritylium ion (= Crystal violet) | E Param.: -11.26 | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | ||
(E)-3-(4-nitro-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO) | DMSO | E Param.: -17.33 | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
(E)-3-(4-cyano-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO) | DMSO | E Param.: -17.64 | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
(E)-1,3-diphenylprop-2-en-1-one (in DMSO) | DMSO | E Param.: -19.39 | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 | |
(E)-4-(4-nitrophenyl)but-3-en-2-one (in DSMO) | DMSO | E Param.: -19.36 | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
(E)-4-methyl-1-(4-nitrophenyl)pent-1-en-3-one (in DMSO) | DMSO | E Param.: -19.17 | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
(E)-4,4-dimethyl-1-(4-nitrophenyl)pent-1-en-3-one | DMSO | E Param.: -19.15 | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
3-chloro-benzaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | ||
3-fluoro-benzaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | ||
3-methoxy-benzaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | ||
4-fluoro-benzaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | ||
benzaldehyde (in DMSO) | DMSO | E Param.: -12.90 | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 | |
hexanal (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | ||
butanal (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | ||
cinnamaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | ||
p-nitro-cinnamaldehyde (in DMSO) | DMSO | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | ||
(E)-N-benzylidene-4-methylbenzenesulfonamide (in DMSO) | DMSO | E Param.: -11.50 | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
(E)-N-(4-methoxybenzylidene)-4-methylbenzenesulfonamide (in DMSO) | DMSO | E Param.: -13.05 | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
(E)-N-(4-(dimethylamino)benzylidene)-4-methylbenzenesulfonamide (in DMSO) | DMSO | E Param.: -15.09 | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
(E)-tert-butyl benzylidenecarbamate (in DMSO) | DMSO | E Param.: -14.22 | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
(E)-N-benzylidene-P,P-diphenylphosphinic amide | DMSO | E Param.: -15.89 | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
(4-F)-tritylium ion | E Param.: 0.35 | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | ||
(4-F)2-tritylium ion | E Param.: 0.17 | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | ||
(4-F)3-tritylium ion | E Param.: 0.05 | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | ||
(3-F)-tritylium ion | E Param.: 1.01 | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | ||
(3-F)2-tritylium ion | E Param.: 1.54 | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | ||
(3-F)3-tritylium ion | E Param.: 2.07 | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | ||
(3-F)4-tritylium ion | E Param.: 2.54 | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | ||
diarylallylium ion (3,3-F2)2 | E Param.: 6.11 | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | ||
diarylallylium ion (3-F)2 | E Param.: 4.15 | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | ||
diarylallylium ion (4-Br)2 | E Param.: 2.85 | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | ||
diarylallylium ion (4-Cl)2 | E Param.: 2.69 | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | ||
diphenylallylium ion | E Param.: 2.70 | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | ||
di-p-tolyl-allylium ion | E Param.: 1.23 | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | ||
di-p-anisyl-allylium ion | E Param.: -1.45 | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | ||
diarylallylium ion (4-NMe2)2 | E Param.: -7.50 | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | ||
bis(julidin-9-yl)allylium ion | E Param.: -9.78 | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | ||
4-methoxy-<i>trans-beta</i>-nitrostyrene | E Param.: -14.70 | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | ||
4-methyl-<i>trans-beta</i>-nitrostyrene | E Param.: -14.23 | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u |