Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
2-cinnamoyl-1,3-dimethyl-1H-imidazol-3-ium	DMSO	E Param.: -11.52	Angew. Chem. Int. Ed. 2012, 51, 5234-5238 10.1002/anie.201109042
(S,E)-2,2,3-trimethyl-4-oxo-5-((perfluorophenyl)methyl)-1-((E)-3-phenylallylidene)imidazolidin-1-ium	dichloromethane	E Param.: -6.00	Angew. Chem. Int. Ed. 2013, 52, 7967-7971 10.1002/anie.201301864
(S,E)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)-5-(3,4,5-trimethoxybenzyl)imidazolidin-1-ium	dichloromethane	E Param.: -7.00	Angew. Chem. Int. Ed. 2013, 52, 7967-7971 10.1002/anie.201301864
ethenesulfonyl fluoride (ESF)	DMSO	E Param.: -12.09	Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875
2-phenylethene-1-sulfonyl fluoride	DMSO	E Param.: -16.63	Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875
N-(phenylsulfonyl)-N-((trifluoromethyl)thio)benzenesulfonamide		E Param.: -6.06	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
N-(trifluoromethyl)thio)phthalimide		E Param.: -11.92	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
N-(trifluoromethyl)thio)saccharin		E Param.: -6.48	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
N-(trifluoromethyl)thio)succinimide		E Param.: -12.56	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
N-(difluoromethyl)thio)phthalimide		E Param.: -11.86	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
N-methyl-N-((trifluoromethyl)thio)-p-toluenesulfonamide		E Param.: -13.44	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
N-methyl-N-((trifluoromethyl)thio)-aniline		E Param.: -23.32	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
((2-phenylpropan-2-yl)oxy)(trifluoromethyl)sulfane		E Param.: -13.77	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane		E Param.: -14.52	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
4-phenylbut-3-yn-2-one		E Param.: -16.90	Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803
hex-3-yn-2-one		E Param.: -17.90	Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803
butynone		E Param.: -16.60	Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803
pop(tol)CH+		E Param.: 2.16	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
fc(ani)CH+		E Param.: -2.90	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
fc(Me)CH+		E Param.: -2.57	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c