Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
2-(4-methoxybenzylidene)-1,3-dithiane 1,1,3,3-tetraoxide	DMSO	E Param.: -14.55	Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046
MacMillan-iminium ion (2nd generation)	MeCN	E Param.: -5.52	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
MacMillan-iminium ion (spiro)	MeCN	E Param.: -7.67	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph)		E Param.: -14.14	Organometallics 2012, 31, 2416-2424 10.1021/om3000357
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl)		E Param.: -14.21	Organometallics 2012, 31, 2416-2424 10.1021/om3000357
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl)		E Param.: -14.46	Organometallics 2012, 31, 2416-2424 10.1021/om3000357
2-cinnamoyl-1,3-dimethyl-1H-imidazol-3-ium	DMSO	E Param.: -11.52	Angew. Chem. Int. Ed. 2012, 51, 5234-5238 10.1002/anie.201109042
PhCH=N+Me2 (in MeCN)	MeCN	E Param.: -9.27	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
pTolCH=N+CH2 (in MeCN)	MeCN	E Param.: -9.64	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
p-AniCH=N+Me2 (in MeCN)	MeCN	E Param.: -10.69	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x