Mayr's Database of Reactivity Parameters

Enamines, Enamides, and Ynamides

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles
1 | 2 | 3 | 4 « Back Found 74 molecules, displaying page 1 of 4 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
(2S,5S)-5-benzyl-2-(tert-butyl)-3-methyl-1-((E)-styryl)imidazolidin-4-one
C23H28N2O*
 MeCN

N  Param.: 5.80

sN Param.: 0.87		***Angew. Chem. Int. Ed. 2012, 51, 5739-5742
10.1002/anie.201201240
(bis(trimethylsiloxy)amino)styrene
C14H25NO2Si2*
 dichloromethane

N  Param.: 4.80

sN Param.: 0.86		*J. Org. Chem. 2001, 66, 3196-3200
10.1021/jo0015927
(cyclohexen-1-yl)prolinate (in MeCN)
*
 MeCN

N  Param.: 18.86

sN Param.: 0.70		***Angew. Chem. Int. Ed. 2010, 49, 9526-9529
10.1002/anie.201004344
(E)-1-(1,2-diphenylvinyl)piperidine (in MeCN)
*
 MeCN

N  Param.: 9.94

sN Param.: 0.86		***Chem. Eur. J. 2018, 24, 5901-5910
10.1002/chem.201705962
(E)-1-(1,2-diphenylvinyl)pyrrolidine (in MeCN)
*
 MeCN

N  Param.: 11.66

sN Param.: 0.82		***Chem. Eur. J. 2018, 24, 5901-5910
10.1002/chem.201705962
(E)-1-(2-(4-methoxyphenyl)-1-phenylvinyl)pyrrolidine (in MeCN)
*
 MeCN

N  Param.: 11.99

sN Param.: 0.84		***Chem. Eur. J. 2018, 24, 5901-5910
10.1002/chem.201705962
(E)-1-(2-(4-nitrophenyl)-1-phenylvinyl)pyrrolidine (in MeCN)
*
 MeCN

N  Param.: 10.42

sN Param.: 0.82		***Chem. Eur. J. 2018, 24, 5901-5910
10.1002/chem.201705962
(E)-1-(N-morpholino)propene
C7H13NO*
 dichloromethane

N  Param.: 12.06

sN Param.: 0.80		*Chem. Eur. J. 2003, 9, 2209-2218
10.1002/chem.200204666
(E)-1-styryl-2-(triphenylsilyl)pyrrolidine (in CH2Cl2)
C30H29NSi*
 dichloromethane

N  Param.: 11.77

sN Param.: 0.98		***J. Am. Chem. Soc. 2014, 136, 14263-14269
10.1021/ja508065e
(E)-1-styryl-2-tritylpyrrolidine (in CH2Cl2)
C31H29N*
 dichloromethane

N  Param.: 10.19

sN Param.: 1.06		***J. Am. Chem. Soc. 2014, 136, 14263-14269
10.1021/ja508065e
(E)-1-styrylpyrrolidine (in CH2Cl2)
C12H15N*
 dichloromethane

N  Param.: 12.26

sN Param.: 0.93		***J. Am. Chem. Soc. 2014, 136, 14263-14269
10.1021/ja508065e
(E)-1-styrylpyrrolidine (in MeCN)
C12H15N*
 MeCN

N  Param.: 13.87

sN Param.: 0.76		***Chem. Eur. J. 2018, 24, 5901-5910
10.1002/chem.201705962
(E)-13-(ethylthio)-6-styryl-6,12-diazadispiro[4.1.47.25]tridec-12-ene (in MeCN)
C21H28N2S*
 MeCN

N  Param.: 7.79

sN Param.: 0.87		***Chem. Eur. J. 2024, 30, e202302764
10.1002/chem.202302764
(E)-2,2,3,5,5-pentamethyl-1-styrylimidazolidin-4-one (in MeCN)
C16H22N2O*
 MeCN

N  Param.: 7.10

sN Param.: 0.82		***Chem. Eur. J. 2024, 30, e202302764
10.1002/chem.202302764
(E)-2,2,3,5,5-pentamethyl-1-styrylimidazolidine-4-thione (in MeCN)
C16H22N2S*
 MeCN

N  Param.: 6.49

sN Param.: 0.83		***Chem. Eur. J. 2024, 30, e202302764
10.1002/chem.202302764
(E)-2-((1-(but-1-en-1-yl)-2,2,5,5-tetramethyl-2,5-dihydro-1H-imidazol-4-yl)thio)acetonitrile (in MeCN)
C13H21N3S*
 MeCN

N  Param.: 9.23

sN Param.: 0.74		***Chem. Eur. J. 2024, 30, e202302764
10.1002/chem.202302764
(E)-4-(1,2-diphenylvinyl)morpholine (in MeCN)
*
 MeCN

N  Param.: 8.78

sN Param.: 0.83		***Chem. Eur. J. 2018, 24, 5901-5910
10.1002/chem.201705962
(E)-4-(2-phenyl-2-(pyrrolidin-1-yl)vinyl)benzonitrile (in MeCN)
*
 MeCN

N  Param.: 10.63

sN Param.: 0.84		***Chem. Eur. J. 2018, 24, 5901-5910
10.1002/chem.201705962
(E)-4-(benzylthio)-2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazole (in CH2Cl2)
C22H26N2S *
 dichloromethane

N  Param.: 7.99

sN Param.: 0.98		***Chem. Eur. J. 2024, 30, e202302764
10.1002/chem.202302764
(E)-4-(benzylthio)-2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazole (in MeCN)
C22H26N2S*
 MeCN

N  Param.: 8.30

sN Param.: 0.84		***Chem. Eur. J. 2024, 30, e202302764
10.1002/chem.202302764