Mayr's Database of Reactivity Parameters

Diazo Compounds and Hydrazones

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
diethyl diazomalonate
C7H10N2O4*
 dichloromethane

N  Param.: -0.35

sN Param.: 0.93		**Chem. Eur. J. 2003, 9, 4068-4076
10.1002/chem.200304913
dimethyl diazomalonate
C5H6N2O4*
 dichloromethane

N  Param.: -1.24

sN Param.: 0.81		***J. Am. Chem. Soc. 2023, 145, 7416-7434
10.1021/jacs.2c13872