Mayr's Database of Reactivity Parameters

Diazo Compounds and Hydrazones

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Diazo Compounds and Hydrazones

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
methyl diazoacetate
C3H4N2O2 *
 dichloromethane

N  Param.: 4.68

sN Param.: 0.94		 *** J. Am. Chem. Soc. 2023, 145, 7416-7434
10.1021/jacs.2c13872
dimethyl diazomalonate
C5H6N2O4 *
 dichloromethane

N  Param.: -1.24

sN Param.: 0.81		 *** J. Am. Chem. Soc. 2023, 145, 7416-7434
10.1021/jacs.2c13872