Mayr's Database of Reactivity Parameters

Isonitriles

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Isonitriles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
tert-butyl isocyanide
C5H9N *
 dichloromethane

N  Param.: 5.47

sN Param.: 0.77		 *** Angew. Chem. Int. Ed. 2007, 46, 3563-3566
10.1002/anie.200605205
benzyl isocyanide
C8H7N *
 dichloromethane

N  Param.: 4.90

sN Param.: 0.74		 *** Angew. Chem. Int. Ed. 2007, 46, 3563-3566
10.1002/anie.200605205
2,6-dimethylphenyl isocyanide
C9H9N *
 dichloromethane

N  Param.: 4.59

sN Param.: 0.87		 *** Angew. Chem. Int. Ed. 2007, 46, 3563-3566
10.1002/anie.200605205
p-tosylmethyl isocyanide (TosMIC)
C9H9NO2S *
 dichloromethane

N  Param.: 3.50

sN Param.: 0.76		 *** Angew. Chem. Int. Ed. 2007, 46, 3563-3566
10.1002/anie.200605205
4-cyanophenyl isocyanide
C8H4N2 *
 dichloromethane

N  Param.: 3.57

sN Param.: 0.72		 ** Angew. Chem. Int. Ed. 2007, 46, 3563-3566
10.1002/anie.200605205