Mayr's Database of Reactivity Parameters

Electrophiles

For reactivities of structurally related compounds go to: Electrophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
ani(tol)CH+
C15H15O *

E Param.: 1.48

 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
pop(Ph)CH+
C19H15O *

E Param.: 2.90

 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
tol(Ph)CH+
C14H13 *

E Param.: 4.43

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(pfp)2CH+
C13H9F2 *

E Param.: 5.01, Deviation: ±0.05

 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
pop(tol)CH+
C20H17O *

E Param.: 2.16, Deviation: ±0.03

 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
fc(Ph)CH+
C17H15Fe *

E Param.: -2.64

 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
fc(ani)CH+
C18H17FeO *

E Param.: -2.90, Deviation: ±0.09

 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
fc(Me)CH+
C12H13Fe *

E Param.: -2.57

 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
fc2CH+
C21H19Fe2 *

E Param.: -8.54, Deviation: ±0.53

 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
C7H7+-Fe(CO)3
*

E Param.: -3.49, Deviation: ±0.17

 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c