Mayr's Database of Reactivity Parameters

H-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
dimethyl((trimethylgermyl)methyl)silane
C6H18GeSi *
 dichloromethane

N  Param.: 5.36

sN Param.: 0.62		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dimethyl((trimethylstannyl)methyl)silane
C6H18SiSn *
 dichloromethane

N  Param.: 6.53

sN Param.: 0.58		 ** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
((methylsilanediyl)bis(methylene))bis(trimethylsilane)
C9H26Si3 *
 dichloromethane

N  Param.: 4.91

sN Param.: 0.64		 ** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tris((trimethylsilyl)methyl)silane
C12H34Si4 *
 dichloromethane

N  Param.: 3.59

sN Param.: 0.67		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tris((butyldimethylsilyl)methyl)silane
C21H52Si4 *
 dichloromethane

N  Param.: 3.73

sN Param.: 0.68		 ** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tris((dimethyl(phenyl)silyl)methyl)silane
C27H40Si4 *
 dichloromethane

N  Param.: 3.40

sN Param.: 0.66		 ** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
cycloheptatriene (in MeCN)
C7H8 *
 MeCN

N  Param.: 0.55

sN Param.: 0.97		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-cyclohexadiene (in MeCN)
*
 MeCN

N  Param.: 0.35

sN Param.: 0.98		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-dioxolane
C3H6O2 *
 dichloromethane

N  Param.: -2.86

sN Param.: 0.80		 *** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-propyl-1,3-dioxolane
C6H12O2 *
 dichloromethane

N  Param.: -1.06

sN Param.: 0.81		 *** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839