H-Si hydride donors
Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
---|---|---|---|---|
triethylsilane | dichloromethane | N Param.: 3.58 sN Param.: 0.70 | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
phenylsilane | dichloromethane | N Param.: 0.06 sN Param.: 0.71 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
triphenylsilane | dichloromethane | N Param.: 2.65 sN Param.: 0.72 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
dimethyl(phenyl)silane | dichloromethane | N Param.: 3.55 sN Param.: 0.75 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
tributylsilane | dichloromethane | N Param.: 3.99 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
trimethylsilane | dichloromethane | N Param.: 3.15 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
ethyldimethylsilane | dichloromethane | N Param.: 3.30 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
diethyl(methyl)silane | dichloromethane | N Param.: 3.40 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
dimethyl(p-tolyl)silane | dichloromethane | N Param.: 3.83 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
(4-methoxyphenyl)dimethylsilane | dichloromethane | N Param.: 4.23 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
(4-chlorophenyl)dimethylsilane | dichloromethane | N Param.: 3.05 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
methyldiphenylsilane | dichloromethane | N Param.: 2.72 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
methyl(phenyl)silane | dichloromethane | N Param.: 2.13 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
diphenylsilane | dichloromethane | N Param.: 1.52 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
tripropylsilane | dichloromethane | N Param.: 3.67 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
triisopropylsilane | dichloromethane | N Param.: 2.93 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
trihexylsilane | dichloromethane | N Param.: 3.89 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
dihexylsilane | dichloromethane | N Param.: 2.27 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
hexylsilane | dichloromethane | N Param.: 0.19 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
(chloromethyl)dimethylsilane | dichloromethane | N Param.: 0.80 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
benzyldimethylsilane | dichloromethane | N Param.: 2.78 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
chlorodimethylsilane | dichloromethane | N Param.: 0.79 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
dichloro(methyl)silane | dichloromethane | N Param.: -3.20 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
1,1,1,3,3-pentamethyldisiloxane | dichloromethane | N Param.: 3.12 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane | dichloromethane | N Param.: 3.61 sN Param.: 0.79 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
dimethyl(neopentyl)silane | dichloromethane | N Param.: 3.55 sN Param.: 0.73 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
((dimethylsilyl)methyl)trimethylsilane | dichloromethane | N Param.: 4.86 sN Param.: 0.64 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
dimethyl((trimethylgermyl)methyl)silane | dichloromethane | N Param.: 5.36 sN Param.: 0.62 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
dimethyl((trimethylstannyl)methyl)silane | dichloromethane | N Param.: 6.53 sN Param.: 0.58 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
((methylsilanediyl)bis(methylene))bis(trimethylsilane) | dichloromethane | N Param.: 4.91 sN Param.: 0.64 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
tris((trimethylsilyl)methyl)silane | dichloromethane | N Param.: 3.59 sN Param.: 0.67 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
tris((butyldimethylsilyl)methyl)silane | dichloromethane | N Param.: 3.73 sN Param.: 0.68 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
tris((dimethyl(phenyl)silyl)methyl)silane | dichloromethane | N Param.: 3.40 sN Param.: 0.66 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
methyl(neopentyl)(phenyl)silane | dichloromethane | N Param.: 0.87 sN Param.: 0.75 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
(3-chlorobenzyl)dimethylsilane | dichloromethane | N Param.: 1.30 sN Param.: 0.75 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
1-methylsiletane | dichloromethane | N Param.: 2.30 sN Param.: 0.75 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
1-methylsilolane | dichloromethane | N Param.: 2.20 sN Param.: 0.75 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
triethoxysilane | dichloromethane | N Param.: -1.80 sN Param.: 0.75 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 | |
dimethyl(propoxy)silane | dichloromethane | N Param.: 2.40 sN Param.: 0.75 | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |