Mayr's Database of Reactivity Parameters

H-Si hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-Si hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
tris((trimethylsilyl)methyl)silane
C12H34Si4 *
 dichloromethane

N  Param.: 3.59

sN Param.: 0.67		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tris((butyldimethylsilyl)methyl)silane
C21H52Si4 *
 dichloromethane

N  Param.: 3.73

sN Param.: 0.68		 ** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tris((dimethyl(phenyl)silyl)methyl)silane
C27H40Si4 *
 dichloromethane

N  Param.: 3.40

sN Param.: 0.66		 ** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
methyl(neopentyl)(phenyl)silane
C12H20Si *
 dichloromethane

N  Param.: 0.87

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(3-chlorobenzyl)dimethylsilane
C9H13ClSi *
 dichloromethane

N  Param.: 1.30

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1-methylsiletane
C4H10Si *
 dichloromethane

N  Param.: 2.30

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1-methylsilolane
C5H12Si *
 dichloromethane

N  Param.: 2.20

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
triethoxysilane
C6H16O3Si *
 dichloromethane

N  Param.: -1.80

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dimethyl(propoxy)silane
C5H14OSi *
 dichloromethane

N  Param.: 2.40

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839