Mayr's Database of Reactivity Parameters

H-B hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
[H-B(C6F5)3]- [NEt4]+
*
 MeCN

N  Param.: 10.04

sN Param.: 0.73		***Angew. Chem. Int. Ed. 2015, 54, 14508-14512
10.1002/anie.201507298
[H-B(2,4,6-F3C6H2)3]- [NEt4]+
*
 MeCN

N  Param.: 14.13

sN Param.: 0.61		***Angew. Chem. Int. Ed. 2015, 54, 14508-14512
10.1002/anie.201507298
[H-B(2,6-F2C6H3)3]- [NEt4]+
*
 MeCN

N  Param.: 13.97

sN Param.: 0.66		***Angew. Chem. Int. Ed. 2015, 54, 14508-14512
10.1002/anie.201507298