Mayr's Database of Reactivity Parameters

H-B hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-B hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
borane-N,N-diethylaniline-complex
*
 dichloromethane

N  Param.: 8.53

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-N-ethyl-N-isopropylaniline-complex
*
 dichloromethane

N  Param.: 9.12

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-N,N-diisopropylaniline-complex
*
 dichloromethane

N  Param.: 8.84

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-2,6-lutidine-complex
*
 dichloromethane

N  Param.: 10.33

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-pyridine-complex
*
 dichloromethane

N  Param.: 10.01

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-4-tBu-pyridine-complex
*
 dichloromethane

N  Param.: 10.46

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-4-methoxypyridine-complex
*
 dichloromethane

N  Param.: 11.01

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-DMAP-complex
*
 dichloromethane

N  Param.: 12.44

sN Param.: 0.76		 *** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetrahydroborate ion (in water)
*
 water

N  Param.: 12.10

sN Param.: 0.79		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
cyanoborate ion (in water)
*
 water

N  Param.: 9.99

sN Param.: 0.54		 *** Org. Biomol. Chem. 2023, 21, 85-88
10.1039/D2OB02041F