H-B hydride donors
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| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
KBH4 (in DMSO)  |
DMSO | N Param.: 15.14 sN Param.: 0.77 |  | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 10.1002/anie.200804263 |
Bu4NBH4 (in DMSO) |
DMSO | N Param.: 14.94 sN Param.: 0.79 | | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 10.1002/anie.200804263 |
NaBH4 (in DMSO) |
DMSO | N Param.: 14.74 sN Param.: 0.81 | | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 10.1002/anie.200804263 |
NaB(OAc)3H (in DMSO) |
DMSO | N Param.: 14.45 sN Param.: 0.76 | | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 10.1002/anie.200804263 |
[H-B(2,4,6-F3C6H2)3]- [NEt4]+ |
MeCN | N Param.: 14.13 sN Param.: 0.61 | | Angew. Chem. Int. Ed. 2015, 54, 14508-14512 10.1002/anie.201507298 |
[H-B(2,6-F2C6H3)3]- [NEt4]+ |
MeCN | N Param.: 13.97 sN Param.: 0.66 | | Angew. Chem. Int. Ed. 2015, 54, 14508-14512 10.1002/anie.201507298 |
borane-DMAP-complex |
dichloromethane | N Param.: 12.44 sN Param.: 0.76 | | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |
tetrahydroborate ion (in water) |
water | N Param.: 12.10 sN Param.: 0.79 |  | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |
Me2 Imd boronate |
dichloromethane | N Param.: 11.88 sN Param.: 0.71 | | Org. Lett. 2012, 14, 82-85 10.1021/ol202836p |
NaBH3(CN) (in DMSO) |
DMSO | N Param.: 11.52 sN Param.: 0.67 | | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 10.1002/anie.200804263 |