H-B hydride donors
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| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
borane-triethylamine-complex  |
dichloromethane | N Param.: 8.90 sN Param.: 0.75 |  | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
NaBH4 (in DMSO) |
DMSO | N Param.: 14.74 sN Param.: 0.81 | | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 10.1002/anie.200804263 |
KBH4 (in DMSO) |
DMSO | N Param.: 15.14 sN Param.: 0.77 | | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 10.1002/anie.200804263 |
Bu4NBH4 (in DMSO) |
DMSO | N Param.: 14.94 sN Param.: 0.79 | | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 10.1002/anie.200804263 |
NaB(OAc)3H (in DMSO) |
DMSO | N Param.: 14.45 sN Param.: 0.76 | | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 10.1002/anie.200804263 |
NaBH3(CN) (in DMSO) |
DMSO | N Param.: 11.52 sN Param.: 0.67 | | Angew. Chem. Int. Ed. 2009, 48, 1958-1961 10.1002/anie.200804263 |
dipp Imd boronate |
dichloromethane | N Param.: 9.55 sN Param.: 0.81 | | Org. Lett. 2012, 14, 82-85 10.1021/ol202836p |
Me2 Imd boronate |
dichloromethane | N Param.: 11.88 sN Param.: 0.71 | | Org. Lett. 2012, 14, 82-85 10.1021/ol202836p |
bromoborane-triethylamine-complex |
dichloromethane | N Param.: 7.49 sN Param.: 0.75 | | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |
borane-trimethylamine-complex |
dichloromethane | N Param.: 7.97 sN Param.: 0.75 | | Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |