Mayr's Database of Reactivity Parameters

Halide Anions

For reactivities of structurally related compounds go to: Nucleophiles
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
bromide (in CF3CH2OH)
Br*
 TFE

N  Param.: 11.70

sN Param.: 0.60		*J. Am. Chem. Soc. 2005, 127, 2641-2649
10.1021/ja045562n
fluoride (in MeOH)
F*
 MeOH

N  Param.: 11.31

sN Param.: 0.63		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 80% aq EtOH)
F*
 water-EtOH mix

N  Param.: 13.20

sN Param.: 0.53		*J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in water)
F*
 water

N  Param.: 7.70

sN Param.: 0.66		*J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 10 % aq MeCN)
F*
 water-MeCN mix

N  Param.: 8.05

sN Param.: 0.64		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 60% aq MeCN)
F*
 water-MeCN mix

N  Param.: 9.75

sN Param.: 0.63		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 80% aq MeCN)
F*
 water-MeCN mix

N  Param.: 11.40

sN Param.: 0.59		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 90% aq MeCN)
F*
 water-MeCN mix

N  Param.: 12.27

sN Param.: 0.59		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z
fluoride (in 98% aq MeCN)
F*
 water-MeCN mix

N  Param.: 10.88

sN Param.: 0.83		***J. Org. Chem. 2012, 77, 3325-3335
10.1021/jo300141z