Halide Anions
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
chloride (in MeOH)   |
MeOH | N Param.: 12.90 sN Param.: 0.60 |
 |
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 50/50 MeOH/MeCN)  |
MeOH-MeCN mix | N Param.: 14.10 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in EtOH)  |
EtOH | N Param.: 14.70 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 80% aq EtOH)  |
water-EtOH mix | N Param.: 13.00 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 50% aq EtOH)  |
water-EtOH mix | N Param.: 11.80 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in H2O)  |
water | N Param.: 10.10 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 20% aq MeCN)  |
water-MeCN mix | N Param.: 11.31 sN Param.: 0.58 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 40% aq MeCN)  |
water-MeCN mix | N Param.: 11.30 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 50% aq MeCN)  |
water-MeCN mix | N Param.: 12.00 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 60% aq MeCN)  |
water-MeCN mix | N Param.: 12.00 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 80% aq MeCN)  |
water-MeCN mix | N Param.: 13.30 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in MeCN)  |
MeCN | N Param.: 17.20 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in CF3CH2OH)  |
TFE | N Param.: 10.30 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in hexafluoroisopropanol)  |
HFIP | N Param.: 8.00 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in 80% aq EtOH)  |
water-EtOH mix | N Param.: 14.50 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in 50% aq EtOH)  |
water-EtOH mix | N Param.: 13.60 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in H2O)  |
water | N Param.: 11.70 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in 20% aq MeCN)  |
water-MeCN mix | N Param.: 12.20 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in 40% aq MeCN)  |
water-MeCN mix | N Param.: 12.80 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in 50% aq MeCN)  |
water-MeCN mix | N Param.: 13.80 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in CF3CH2OH)  |
TFE | N Param.: 11.70 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
fluoride (in MeOH)  |
MeOH | N Param.: 11.31 sN Param.: 0.63 |
|
J. Org. Chem. 2012, 77, 3325-3335 10.1021/jo300141z |
fluoride (in 80% aq EtOH)  |
water-EtOH mix | N Param.: 13.20 sN Param.: 0.53 |
|
J. Org. Chem. 2012, 77, 3325-3335 10.1021/jo300141z |
fluoride (in water)  |
water | N Param.: 7.70 sN Param.: 0.66 |
|
J. Org. Chem. 2012, 77, 3325-3335 10.1021/jo300141z |
fluoride (in 10 % aq MeCN)  |
water-MeCN mix | N Param.: 8.05 sN Param.: 0.64 |
|
J. Org. Chem. 2012, 77, 3325-3335 10.1021/jo300141z |
fluoride (in 60% aq MeCN)  |
water-MeCN mix | N Param.: 9.75 sN Param.: 0.63 |
|
J. Org. Chem. 2012, 77, 3325-3335 10.1021/jo300141z |
fluoride (in 80% aq MeCN)  |
water-MeCN mix | N Param.: 11.40 sN Param.: 0.59 |
|
J. Org. Chem. 2012, 77, 3325-3335 10.1021/jo300141z |
fluoride (in 90% aq MeCN)  |
water-MeCN mix | N Param.: 12.27 sN Param.: 0.59 |
|
J. Org. Chem. 2012, 77, 3325-3335 10.1021/jo300141z |
fluoride (in 98% aq MeCN)  |
water-MeCN mix | N Param.: 10.88 sN Param.: 0.83 |
|
J. Org. Chem. 2012, 77, 3325-3335 10.1021/jo300141z |