Mayr's Database of Reactivity Parameters

N-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
propargylamine (in water)
C3H5N *
 water

N  Param.: 12.29

sN Param.: 0.59		 *** J. Org. Chem. 2007, 72, 3679-3688
10.1021/jo062586z
allylamine (in water)
C3H7N *
 water

N  Param.: 13.21

sN Param.: 0.54		 *** J. Org. Chem. 2007, 72, 3679-3688
10.1021/jo062586z
benzylamine (in water)
C7H9N *
 water

N  Param.: 13.44

sN Param.: 0.55		 *** J. Org. Chem. 2007, 72, 3679-3688
10.1021/jo062586z
4-chloroaniline (in MeCN)
C6H6ClN *
 MeCN

N  Param.: 12.92

sN Param.: 0.60		 *** J. Org. Chem. 2007, 72, 3679-3688
10.1021/jo062586z
aniline (in water)
C6H7N *
 water

N  Param.: 12.99

sN Param.: 0.73		 *** J. Org. Chem. 2007, 72, 3679-3688
10.1021/jo062586z
aniline (in MeCN)
C6H7N *
 MeCN

N  Param.: 12.64

sN Param.: 0.68		 *** J. Org. Chem. 2007, 72, 3679-3688
10.1021/jo062586z
p-toluidine (in water)
C7H9N *
 water

N  Param.: 13.00

sN Param.: 0.79		 *** J. Org. Chem. 2007, 72, 3679-3688
10.1021/jo062586z
p-toluidine (in MeCN)
C7H9N *
 MeCN

N  Param.: 13.19

sN Param.: 0.69		 *** J. Org. Chem. 2007, 72, 3679-3688
10.1021/jo062586z
4-methoxyaniline (in water)
C7H9NO *
 water

N  Param.: 14.28

sN Param.: 0.68		 *** ChemPlusChem 2015, 80, 1673-1679
10.1002/cplu.201500246
4-methoxyaniline (in MeCN)
C7H9NO *
 MeCN

N  Param.: 13.42

sN Param.: 0.73		 *** J. Org. Chem. 2007, 72, 3679-3688
10.1021/jo062586z